Name: Norio Nakata
Present Address: Department of Chemistry, Graduate School of Science and Engineering, Saitama University
255, Shimo-Okubo, Sakura-ku, Saitama, 338-8570, Japan
Tel: +81-48-858-3392
Fax: +81-48-858-3700
e-mail: nakata<at>chem.saitama-u.ac.jp
ReseacherID: B-4017-2012
Education:
1998 B.Eng. at Department of Chemistry, Faculty of Engineering, Gifu University
(Supervisor Prof. Shinzi Kato)
2000 M.Eng. at Department of Chemistry, Faculty of Engineering, Gifu University
(Supervisor Prof. Shinzi Kato, Thesis entitled “Studies on Gallium and
Indium Thio-, Seleno-, and Dithiocarboxylates: Synthesis and Structure)
2003 Ph.D. at Department of Chemistry, Graduate School of Science, Kyoto University
(Supervisor Prof. Norihiro Tokitoh, Thesis entitled “Studies on the Synthesis and Properties of Kinetically Stabilized Germaaromatic Compounds)
Research and Professional Experience:
2003 Postdoctoral Fellow, at Department of Chemistry, University of Tsukuba,
(Prof. Akira Sekiguchi)
Studies on New Doubly Bonded Compounds between a Silicon and Group
13 Element
2004-2006 Research Associate, at Department of Chemistry, University of Tsukuba,
(Prof. Akira Sekiguchi)
Studies on Low-coordinated Compounds Containing a Silicon or Germanium Atom
2006-present Assistant Professor, at Department of Chemistry, Saitama University,
(Prof. Akihiko Ishii)
Organometallic Chemistry, Organoheteroatom Chemistry,
Polymerization Chemistry, Material Science
Accolades:
2001
Poster Award, 6th Symposium of the Society of Silicon Chemistry, Japan
2005 The Chemical Society of Japan Lecture Award for Young Chemists
2008
ADEKA Award in Synthetic Organic Chemistry, Japan
2010
Shionogi Award in Synthetic Organic Chemistry, Japan
2010
Best Poster Award, 24th International Conference on Organometallic Chemistry (Taipei, Taiwan)
2010
Poster Award, 11th International Conference on the Chemistry of Selenium and Tellurium (Oulu, Finland)
List of Publications:
(2011)
1. Palladium(II) Hydrido Complexes Having a Primary Silyl or Germyl Ligand:Synthesis, Crystal Structures, and Dynamic Behavior
N. Nakata, S. Fukazawa, and A. Ishii
Organometallics, (2011), in press.
2. Fluorescent 3-Methylene-2,3-dihydrochalcogenophenes Incorporated in a Rigid Dibenzobarrelene Skeleton
A. Ishii, Y. Yamaguchi, and N. Nakata
Organic Letters, 2, 1597–1610 (2011).
3. Recent Advances in the Chemistry of Group 4 Metal Complexes Incorporating [OSSO]-Type Bis(phenolato) Ligands as Post-metallocene Catalysts
N. Nakata, T. Toda, and A. Ishii
Polymer Chemistry, 2, 1597–1610 (2011).
4. Coordination Chemistry and Organic Synthesis Utilizing Cycloalkane-1,2-dithiol
A. Ishii, T. Toda, N. Nakata, and T.Matsuo
Heteroatom Chemistry, 22, 388–396 (2011).
5. Syntheses, Structures, and Complexation of cis- and trans-Cyclooctane-1,2-diyl-fused Crown Thioethers([1,2]ansS4)
A. Ishii, S. Asami, Y. Fujiwara, A. Ono, and N. Nakata
Heteroatom Chemistry, 22, 388–396 (2011).
6. Synthesis of Ti(IV) and Zr(IV) Complexes with an [OSSO]-type Bis(phenolate) Ligands Bearing a trans-Cyclohexane-1,2-diyl Ring and 1-Hexene Polymerization
A. Ishii, K. Asajima, T. Toda, and N. Nakata
Organometallics, 30, 2947–2956 (2011).
7. Synthesis and Structures of Dialkyl Zirconium Complexes with an[OSSO]-type bis(phenolato) Ligand Bearing a trans-1,2-Cyclooctane-diylbis(thio) unit
T. Toda, N. Nakata, T. Matsuo, andA. Ishii
Journal of Organometallic Chemistry, 696, 1258-1261 (2011).
(2010)
8. Syntheses of Selenolato-Bridged Dinuclear Hydroplatinum Complexes [Pt2H2(μ-SetBu)2(PPh3)2] and [Pt2H(SetBu)(μ-SetBu)2(PPh3)2]: Unusual Thermal Reaction of Hydrido(1,1-dimethylethaneselenolato) Platinum Complex cis-[PtH2(SetBu)2(PPh3)2]
N. Nakata, T. Ikeda, and A. Ishii
Inorganic Chemistry, 49, 8112–8116 (2010).
9. Cleavage of C-S and O-H Bonds by Pt(0) Complexes To Give Five-Membered 1,2-Oxaplatinaycles
N. Nakata, N. Furukawa, T. Toda, and A. Ishii
Angewandte Chemie, International Edition, 49, 5784–5787 (2010).
10. Reactions of 7,8-Dithiabicyclo[4.2.1]nona-2,4-diene 7-exo-Oxide with Dodecacarbonyl Triiron Fe3(CO)12: A Novel Type of Sulfenato Thiolato Diiron Hexacarbonyl Complexes
J. Windhager, U-P. Apfel, T. Yoshino, N. Nakata, H. Görls, M. Rudolph,
A. Ishii, and W.Weigand
Chemisry-An Asian Journal, 5, 1600–1610 (2010).
11. Thermal Reaction of a (Hydrido)(selenolato)Platinum(II) Complex Having a Dibenzyl Group Leading to Three Cyclometalations
A. Ishii, Y. Yamaguchi, and N. Nakata,
Dalton Transaction, 39, 6181–6183 (2010).
12. Synthesis and Properties of Hydrido(Selenolato)Platinum(II) Complexes Bearing Chelating Phosphine Ligands
N. Nakata, T. Yoshino, and A. Ishii
Phosphorus, Sulfur, and Silicon, Related Elements, 185, 992–999 (2010).
13. Spiro[2,5-dibenzo-1,4-disilacyclohexa-2,5-diene-1,7-2,5-dibenzo-1,4,7-trisilanorbornadiene]: Unusual Dimeriation of Silyl-Substituted 9,10-Disila(Dewar Anthracene)
N. Nakata, S. Masubuchi, and A. Sekiguchi
Phosphorus, Sulfur, and Silicon, Related Elements, 185, 957–963 (2010).
14. Hydroselenation and Carboselenation of Electron-Deficient Alkynes with Isolable (Hydrido)(selenolato)platinum(II) Complexes and a Selenaplatinacycle Bearing Triptycene Skelton
A. Ishii, H. Kamon, K. Murakami, and N. Nakata
European Journal of Organic Chemistry, 1653–1659 (2010).
15. Synthesis and Thermal Reaction of Hydrido(selenolato) Platinum(II) Complexe Having a 9,10,11,12,14,15-hexahydro-9,10[3',4']-furano-anthracenyl Group
N. Nakata, Y. Yamaguchi, and A. Ishii
Journal of Organometallic Chemistry, 695, 970–973 (2010).
16. Synthesis, Structure, and Catalytic Activity of Bimetallic Pt(II)-Ir(II) Complexes Bridged by Cyclooctane-1,2-dithiolato Ligands
N. Nakata, M. Sakashita, C. Komatsubara, and A. Ishii
European Journal of Inorganic Chemistry, 447–453 (2010).
(2009)
17. Zirconium Complex of An [OSSO]-Type Diphenolate Ligand Bearing trans-1,2-Cyclooctanediylbis(thio) Core: Synthesis, Structure, and Isospecific 1-Hexene Polymerization
A. Ishii, T. Toda, N. Nakata, and T. Matsuo
Journal of the American Chemical Society, 131, 13566–13567 (2009).
18. Three Syntheses of trans-Cyclooctane-1,2-dithiol by Ring Opening of cis-Cyclooctene Episulfoxide with Ammonium Thiocyanate Followed by Reduction and Reductions of trans-1,2-Di(thiocyanato)cyclooctane and trans-1,2-Cyclooctyl trithiocarbonate
A. Ishii, A. Ono, and N. Nakata
Journal of Sulfur Chemistry, 30, 236–244 (2009).
19. Oxidation and Reduction Reactions of cis-9,10,11-Trithiabicyclo[6.3.0]undecane Synthesized by Reaction of cis-Cyclooctene with S8O
A. Ishii, M. Suzuki, T. Sone, and N. Nakata
Phosphorus, Sulfur, and Silicon, Related Elements,
184,
1184–1205
(2009).
20. Synthesis and X-ray Structural Analysis of Hydrido(thiolato) Platinum(II) Complexes
N. Nakata, S. Yamamoto, W. Hashima and A. Ishii
Chemistry Letters, 38, 400–401 (2009).
21. Reactions of 9-Triptyceneselenol with Pd(0) Complexes: Unexpected Formations of Dinuclear Pd(I) Complex [{Pd(PPh3)}2(μ-SeTrip)2] and Five-membered Selenapalladacycle [Pd(η2-C,Se-Trip)(dppe)]
N. Nakata, R. Uchiumi, T. Yoshino, T. Ikeda, H. Kamon, and A. Ishii
Organometallics, 28, 1981–1984 (2009).
22. Synthesis and Crystal Structures of the First Stable Mononuclear Dihydrogermyl(hydrido) Platinum(II) Complexes
N. Nakata, S. Fukazawa, and A. Ishii
Organometallics, 28, 534–538 (2009).
(2008)
23. 1,3-Digerma-2-gallata- and -indataallenic Anions: The First Compounds with Ge=Ga or Ge=In Double Bonds
N. Nakata, R. Izumi, V. Ya. Lee, M. Ichinohe, and A. Sekiguchi
Chemistry Letters, 37, 1146–1147 (2008).
24. Reactions of a Ditriptycyl-Substituted Selenoseleninate and Related Compounds with a Platinum(0) Complex: Formation of Selenaplatinacycle and Hydrido Selenolato Platinum(II) Complexes
A. Ishii, N. Nakata, R. Uchiumi, and K. Murakami
Angewandte Chemie, International Edition, 47, 2661–2664 (2008).
25. Photochemical Reaction of Silyl-substituted 1,4-Disila(Dewar-benzene) with Isocyanide and Phenylacetylene
T. Oikawa, N. Nakata, T. Matsumoto, Y. Kabe, and A. Sekiguchi
Heteroatom Chemistry, 19, 87–92 (2008).
(2007)
26. Preparation of 3,3-Di-tert-butylthiirane trans-1,2-Dioxide and Its Reaction with a Platinum(0) Complex To Give a (Disulfenato)platinum(II) Complex: Regioselectivity of the Oxidation of a Related (Sulfenato-thiolato)platinum(II) Complex
A. Ishii, M. Ohishi, and N. Nakata
European Journal of Inorganic Chemistry, 5199–5206 (2007).
27. Thia- and Selenasilaboriranes and 1,3,2,4-Dioxasilaboretane from a Stable Silaborene
N. Nakata and A. Sekiguchi
Chemistry Letters, 36, 662–663 (2007).
28. Coordination Chemistry of a Kinetically Stabilized Germabenzene: Syntheses and Properties of Stable η6-Germabenzene Complexes Coordinated with Transition Metals
N. Tokitoh, N. Nakata, A. Shinohara, N. Takeda, and T. Sasamori
Chemisry-A European Journal, 13, 1856–1862 (2007).
(2006)
29. A Stable Schrock-Type Hafnium-Silylene Complex
N. Nakata, T. Fujita, and A. Sekiguchi
Journal of the American Chemical Society, 128, 16024–16025 (2006).
30. Synthesis of 1,4-Disilacyclohexa-2,5-diene-1,4-diide by the Reduction of 1,4-Disilabicyclo-[2.2.0]- hexa-2,5-diene
N. Nakata, T. Oikawa, T. Matsumoto, Y. Kabe, and A. Sekiguchi
Organometallics, 25, 5850–5851 (2006).
31. Synthesis and Characterization of Two Isomers of 14π-electron Germaaromatics: Kinetically Stabilized 9-Germaanthracene and 9-Germaphenanthrene
T. Sasamori, K. Inamura, W. Hoshino, N. Nakata, Y. Mizuhata,
Y. Watanabe, Y. Furukawa, and N. Tokitoh
Organometallics, 25, 3533–3536 (2006).
32. A Stable Silaborene: Synthesis and Characterization
N. Nakata and A. Sekiguchi
Journal of the American Chemical Society, 128, 422–423 (2006).
(2005)
33. Silyl-Substituted 1,4-Disila(Dewar-benzene): New Synthesis and Unexpected Insertion of CO into the Si-Si Bond to Form a Disilyl Ketone
N. Nakata, T. Oikawa, T. Matsumoto, Y. Kabe, and A. Sekiguchi
Organometallics, 24, 3368–3370 (2005).
34. Reaction of Dilithiosilane R2SiLi2 and Dilithiogermane R2GeLi2 (R = SiMetBu2) with MesBCl2 (Mes = 2,4,6-trimethylphenyl): Evidence for the Formation of Silaborene R2Si=BMes and Germaborene R2Ge=BMes
N. Nakata, R. Izumi, V. Ya. Lee, M. Ichinohe, and A. Sekiguchi
Chemistry Letters, 34, 582–583 (2005).
(2004)
35. 1,3-Disila-2-gallata- and -indataalleneic Anions [>Si=M=Si<]- Li+ (M = Ga, In): Compounds Featuring Double Bonds Between Elements of Groups 13 and 14
N. Nakata, R. Izumi, V. Ya. Lee, M. Ichinohe, and A. Sekiguchi
Journal of the American Chemical Society, 126, 4758–4759 (2004).
(2003)
36. Reaction of a Stable Germabenzene with Chalcogens: Synthesis and Structure of a Novel Germanium Analog of Pentathiepane, 1,2,3,4,5,6-Pentathiagermepane
N. Nakata, N. Takeda, and N. Tokitoh
Journal of Organometallic Chemistry, 672, 66–71 (2003).
37.Synthesis and Properties of the First Stable Neutral Germaaromatic Compound, 2-{2,4,6-Tris- [bis(trimethylsilyl)methyl]phenyl}-2-germa-naphthalene
N. Nakata, N. Takeda, and N. Tokitoh
Organometallics, 22, 481–489 (2003).
38. η6-Germabenzene Complexes of Chromium and Molybdenum
N. Nakata, N. Takeda, and N. Tokitoh
Angewandte Chemie, International Edition, 42, 115–117 (2003).
(2002)
39.Reactions of 2-Germanaphthalene with Elemental Sulfur and Selenium: Synthesis of Novel Cyclic Polychalcogenides Containing a Germanium, Trichalcogenagermolanes
N. Nakata, N. Takeda, and N. Tokitoh
Chemistry Letters, 31, 818–819 (2002).
40. Synthesis and Properties of the First Stable Germabenzene
N. Nakata, N. Takeda, and N. Tokitoh
Journal of the American Chemical Society, 124, 6914–6920 (2002).
41. Synthesis and Characterization of an Extremely Hindered Tetraaryl-Substituted Digermene and its Unique Properties in the Solid State and in Solution
N. Tokitoh, K. Kishikawa, R. Okazaki, T. Sasamori, N. Nakata, and
N. Takeda
Polyhedron, 21, 563–577 (2002).
(2001)
42. Synthesis and Structure of a Kinetically Stabilized 2-Germa-naphthalene: The First Stable Neutral Germaaromatic Compound
N. Nakata, N. Takeda, and N. Tokitoh
Organometallics, 20, 5507–5509 (2001).
2011/9/28